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"Soil" Keyword-tagged Publications:
| Title: | Electro-washing of pipelines spills: On-site strategies for different soil matrices | ||||
| Authors: | Rajaei E, Elektorowicz M | ||||
| Link: | https://pubmed.ncbi.nlm.nih.gov/40614426/ | ||||
| DOI: | 10.1016/j.jhazmat.2025.139112 | ||||
| Publication: | Journal of hazardous materials | ||||
| Keywords: | Electro-washing; Multi-components polluted soil; Oil recovery; Petroleum spills; Water reuse; Zwitterionic surfactant; | ||||
| PMID: | 40614426 | Category: | Date Added: | 2025-07-05 | |
| Dept Affiliation: |
ENCS
1 Department of Building, Civil and Environmental Engineering, Concordia University, Montréal, Quebec H3G 1M8, Canada. Electronic address: elnaz.rajaei@concordia.ca. 2 Department of Building, Civil and Environmental Engineering, Concordia University, Montréal, Quebec H3G 1M8, Canada. Electronic address: maria.elektorowicz@concordia.ca. |
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Description: |
Crude oil remains a dominant global energy source but spills from pipelines, and reservoirs pose significant environmental and health risks. Remediating petroleum hydrocarbon (PHC)-contaminated soils is critical yet challenging, especially in fine-grained matrices where conventional methods underperform. In this context, electro-washing (EW), either in-situ or ex-situ with surfactant enhancement, offers a tunable, energy-efficient solution that is adaptable to varying soil textures and voltage gradients. This study demonstrates a low-voltage EW methodology for PHC-polluted soils containing 0-5 % bentonite clay, utilizing a zwitterionic surfactant. Laboratory-scale EW cells treated 1 kg soil samples under 1-3 V/cm for four days. Results show that increasing both the clay fraction and voltage gradient significantly improved PHC removal, achieving up to 88 % reduction in soils with 5 % clay at 3 V/cm. Electroosmotic flow transported pore fluid toward the cathode, while negatively charged surfactant micelles migrated toward the anode via electrophoresis, facilitating the delivery of heavier oil fractions. Additionally, in-situ electro-demulsification enabled oil recovery and clean water separation. A polynomial empirical model correlating clay content and voltage to removal efficiency was developed, yielding an excellent fit (R² ˜ 0.93, p < 0.01) and indicating that both factors significantly influence PHC reduction. This work highlights a novel low-energy electrokinetic-surfactant system capable of overcoming the limitations of conventional washing, especially in clayey soils. The method demonstrates near-regulatory cleanup within days, with the added benefit of resource recovery. A preliminary scale-up analysis confirms the feasibility of EW as a sustainable and field-adaptable remediation strategy. |



