Keyword search (4,164 papers available)

"Velazquez-Garcia JJ" Authored Publications:

Title Authors PubMed ID
1 Synthesis, Characterization and Photophysical Properties of a New Family of Rare-earth Cluster-based Metal-organic Frameworks Bicalho HA; Copeman C; Barbosa HP; Donnarumma PR; Davis Z; Quezada-Novoa V; Velazquez-Garcia JJ; Liu N; Hemmer E; Howarth AJ; 39105655
CHEMBIOCHEM
2 Unravelling the synthesis of a rare-earth cluster-based metal-organic framework with spn topology Bicalho HA; Saraci F; Velazquez-Garcia JJ; Titi HM; Howarth AJ; 36065793
CHEMBIOCHEM

 

Title:Synthesis, Characterization and Photophysical Properties of a New Family of Rare-earth Cluster-based Metal-organic Frameworks
Authors:Bicalho HACopeman CBarbosa HPDonnarumma PRDavis ZQuezada-Novoa VVelazquez-Garcia JJLiu NHemmer EHowarth AJ
Link:https://pubmed.ncbi.nlm.nih.gov/39105655/
DOI:10.1002/chem.202402363
Publication:Chemistry (Weinheim an der Bergstrasse, Germany)
Keywords:metal-organic frameworks, rare-earth MOFs, rare-earth elements, lanthanoid MOFs, lanthanides
PMID:39105655 Category: Date Added:2024-08-06
Dept Affiliation: CHEMBIOCHEM
1 Concordia University, Chemistry and Biochemistry, 7141 Sherbrooke St W, H4B1R6, Montreal, CANADA.
2 University of Ottawa, Chemistry and Biomolecular Sciences, 10 Marie Curie Street, Ottawa, CANADA.
3 Concordia University, Chemistry and Biochemistry, 7141 Sherbrooke St W, Montreal, CANADA.
4 DESY, PhotoScience, Notkestraße 85, Hamburg, GERMANY.
5 University of Ottawa, Chemistry and Biomolecular Sciences, CANADA.

Description:

In this work, nine new rare-earth metal-organic frameworks (RE-MOFs, where RE = Lu(III), Yb(III), Tm(III), Er(III), Ho(III), Dy(III), Tb(III), Gd(III), and Eu(III)) isostructural to Zr-MOF-808 are synthesized, characterized, and studied regarding their photophysical properties. Materials with high crystallinity and surface area are obtained from a reproducible synthetic procedure that involves the use of two fluorinated modulators. At the same time, these new RE-MOFs display tunable photoluminescent properties due to efficient linker-to-metal energy transfer promoted by the antenna effect, resulting in a series of RE-MOFs displaying lanthanoid-based emissions spanning the visible and near-infrared regions of the electromagnetic spectrum.





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