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PubMed Publications| Keyword search (4,163 papers available) |  |
"Sheibany N" Authored Publications:
| Title | Authors | PubMed ID | |
|---|---|---|---|
| 1 | Overlap and Covalency in a κN-Arylnitrosyl Cu(II) Metalloradical Formed by Hydroxylamine Oxidative Binding | MacKay A; Zsombor-Pindera J; Effaty F; Sheibany N; Gennarini F; Habibian M; Chen F; Askari MS; Brytskyi M; Kroeker S; Kennepohl P; Ottenwaelder X; | 41524899 CHEMBIOCHEM |
| 2 | Intramolecular H-bond stabilization of a primary hydroxylamine in salen-type metal complexes | Singh H; MacKay A; Sheibany N; Chen F; Mosser M; Rouet PÉ; Rousseau F; Askari MS; Ottenwaelder X; | 34545379 CHEMBIOCHEM |
| Title: | Intramolecular H-bond stabilization of a primary hydroxylamine in salen-type metal complexes | ||||
| Authors: | Singh H, MacKay A, Sheibany N, Chen F, Mosser M, Rouet PÉ, Rousseau F, Askari MS, Ottenwaelder X | ||||
| Link: | https://pubmed.ncbi.nlm.nih.gov/34545379/ | ||||
| DOI: | 10.1039/d1cc03077a | ||||
| Publication: | Chemical communications (Cambridge, England) | ||||
| Keywords: | |||||
| PMID: | 34545379 | Category: | Date Added: | 2021-09-21 | |
| Dept Affiliation: |
CHEMBIOCHEM
1 Department of Chemistry and Biochemistry, Concordia University, Montreal, QC, Canada. dr.x@concordia.ca. |
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Description: |
Primary hydroxylamines, RNHOH, decompose readily in the presence of transition metal ions. We show that this reactivity can be arrested by ligand design via an intramolecular hydrogen bond. Six metal complexes with an intact NHOH group were synthesized and crystallographically characterized. The Cu-hydroxylamine complexes can catalyze the aerobic oxidation of benzylic alcohols. |
