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PubMed Publications| Keyword search (4,164 papers available) |  |
"Rouet PÉ" Authored Publications:
| Title | Authors | PubMed ID | |
|---|---|---|---|
| 1 | Intramolecular H-bond stabilization of a primary hydroxylamine in salen-type metal complexes | Singh H; MacKay A; Sheibany N; Chen F; Mosser M; Rouet PÉ; Rousseau F; Askari MS; Ottenwaelder X; | 34545379 CHEMBIOCHEM |
| Title: | Intramolecular H-bond stabilization of a primary hydroxylamine in salen-type metal complexes | ||||
| Authors: | Singh H, MacKay A, Sheibany N, Chen F, Mosser M, Rouet PÉ, Rousseau F, Askari MS, Ottenwaelder X | ||||
| Link: | https://pubmed.ncbi.nlm.nih.gov/34545379/ | ||||
| DOI: | 10.1039/d1cc03077a | ||||
| Publication: | Chemical communications (Cambridge, England) | ||||
| Keywords: | |||||
| PMID: | 34545379 | Category: | Date Added: | 2021-09-21 | |
| Dept Affiliation: |
CHEMBIOCHEM
1 Department of Chemistry and Biochemistry, Concordia University, Montreal, QC, Canada. dr.x@concordia.ca. |
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Description: |
Primary hydroxylamines, RNHOH, decompose readily in the presence of transition metal ions. We show that this reactivity can be arrested by ligand design via an intramolecular hydrogen bond. Six metal complexes with an intact NHOH group were synthesized and crystallographically characterized. The Cu-hydroxylamine complexes can catalyze the aerobic oxidation of benzylic alcohols. |
