BookR: School of Health Core Facilities Booking
PubMed Publications| Keyword search (4,163 papers available) |  |
"Robert C Mawhinney" Authored Publications:
| Title | Authors | PubMed ID | |
|---|---|---|---|
| 1 | The electronic structure of nitrilimines revisited | Robert C Mawhinney | 15306921 CERMM |
| 2 | Characterizing nitrilimines with nuclear magnetic resonance spectroscopy. A theoretical study | Robert C Mawhinney | 18062684 CHEMBIOCHEM |
| Title: | The electronic structure of nitrilimines revisited | ||||
| Authors: | Robert C Mawhinney | ||||
| Link: | https://pubmed.ncbi.nlm.nih.gov/15306921/ | ||||
| DOI: | 10.1039/b407302a | ||||
| Publication: | Chemical communications (Cambridge, England) | ||||
| Keywords: | |||||
| PMID: | 15306921 | Category: | Date Added: | 2004-08-13 | |
| Dept Affiliation: |
CERMM
1 Centre for Research in Molecular Modeling and Department of Chemistry & Biochemistry, Concordia University, 7141 Sherbrooke Street West, Montreal, Quebec, Canada. |
||||
Description: |
A combination of density-functional theory and natural resonance theory has been used to show that a complete description of the electronic structure of nitrilimines, R(1)CNNR(2), requires four resonance structures (propargylic, allenic, 1,3-dipolar and carbenic); appropriate substituents were shown to enhance the carbene character of nitrilimines to the point where they may be considered stable carbenes. |
