Keyword search (4,164 papers available)

"Ricardo-Noordberg J" Authored Publications:

Title Authors PubMed ID
1 Molecular copper(I)-sensitized photoanodes for alcohol oxidation under ambient conditions Ricardo-Noordberg J; Kamal S; Majewski M; 38932662
CHEMBIOCHEM
2 A historical perspective on porphyrin-based metal-organic frameworks and their applications Zhang X; Wasson MC; Shayan M; Berdichevsky EK; Ricardo-Noordberg J; Singh Z; Papazyan EK; Castro AJ; Marino P; Ajoyan Z; Chen Z; Islamoglu T; Howarth AJ; Liu Y; Majewski MB; Katz MJ; Mondloch JE; Farha OK; 33678810
CNSR

 

Title:Molecular copper(I)-sensitized photoanodes for alcohol oxidation under ambient conditions
Authors:Ricardo-Noordberg JKamal SMajewski M
Link:https://pubmed.ncbi.nlm.nih.gov/38932662/
DOI:10.1002/cssc.202400611
Publication:ChemSusChem
Keywords:donor-chromophore-acceptorphotocatalysis, solar energy conversionphotoelectrochemistry
PMID:38932662 Category: Date Added:2024-06-27
Dept Affiliation: CHEMBIOCHEM
1 Concordia University, Chemistry and Biochemistry, CANADA.
2 University of British Columbia, Chemistry, CANADA.
3 Concordia University, Chemistry and Biochemistry, 7141 Sherbrook St W, H4B 1R6, Montreal, CANADA.

Description:

Dye-sensitized photoelectrochemical cells can enable the production of molecules currently accessible through energetically demanding syntheses. Copper(I)-based dyes represent electronically tunable charge transfer and separation systems. Herein, we report a Cu(I)-bisdiimine donor-chromophore-acceptor dye with an absorbance in the visible part of the solar spectrum composed of a phenothiazine electron donor, and dipyrido[3,2-a:2',3'-c]phenazine electron acceptor. This complex is incorporated onto a zinc oxide nanowire semiconductor surface effectively forming a photoanode that is characterized spectroscopically and electrochemically. We investigate the photo-oxidation of hydroquinone, and the photosensitization of 2,2,6,6-tetramethylpiperidine-1-oxyl and N-hydroxyphthalimide for the oxidation of furfuryl alcohol to furfuraldehyde, resulting in near quantitative conversions, with poor selectivity to the alcohol.





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