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PubMed Publications| Keyword search (4,163 papers available) |  |
"Ottenwaelder X" Authored Publications:
| Title | Authors | PubMed ID | |
|---|---|---|---|
| 1 | Overlap and Covalency in a κN-Arylnitrosyl Cu(II) Metalloradical Formed by Hydroxylamine Oxidative Binding | MacKay A; Zsombor-Pindera J; Effaty F; Sheibany N; Gennarini F; Habibian M; Chen F; Askari MS; Brytskyi M; Kroeker S; Kennepohl P; Ottenwaelder X; | 41524899 CHEMBIOCHEM |
| 2 | Mechanochemistry for Metal-Organic Frameworks and Covalent-Organic Frameworks (MOFs, COFs): Methods, Materials, and Mechanisms | Marrett JM; Effaty F; Ottenwaelder X; Frišcic T; | 40708349 CHEMBIOCHEM |
| 3 | Mechanochemical Synthesis of Boroxine-linked Covalent Organic Frameworks | Hamzehpoor E; Effaty F; Borchers TH; Stein RS; Wahrhaftig-Lewis A; Ottenwaelder X; Frišcic T; Perepichka DF; | 38970305 CHEMBIOCHEM |
| 4 | Cooperative Sensitization Upconversion in Solution Dispersions of Co-Crystal Assemblies of Mononuclear Yb3+ and Eu3+ Complexes | Sun G; Xie Y; Wang Y; Mandl GA; Maurizio SL; Zhang H; Ottenwaelder X; Capobianco JA; Sun L; | 37040148 CNSR |
| 5 | Resonant acoustic mixing (RAM) for efficient mechanoredox catalysis without grinding or impact media | Effaty F; Gonnet L; Koenig SG; Nagapudi K; Ottenwaelder X; Frišcic T; | 36546478 CHEMBIOCHEM |
| 6 | Intramolecular H-bond stabilization of a primary hydroxylamine in salen-type metal complexes | Singh H; MacKay A; Sheibany N; Chen F; Mosser M; Rouet PÉ; Rousseau F; Askari MS; Ottenwaelder X; | 34545379 CHEMBIOCHEM |
| 7 | Programmed Synthesis of Tetra-Aryl Thiophenes with Stepwise, Ester-Controlled Regioselectivity | Messina C; Ottenwaelder X; Forgione P; | 34506149 CHEMBIOCHEM |
| 8 | Five Nitrogen Oxidation States from Nitro to Amine: Stabilization and Reactivity of a Metastable Arylhydroxylamine Complex. | Zsombor-Pindera J; Effaty F; Escomel L; Patrick B; Kennepohl P; Ottenwaelder X; | 33124796 CHEMBIOCHEM |
| 9 | Tuning Inner-Sphere Electron Transfer in a Series of Copper/Nitrosoarene Adducts. | Askari MS, Effaty F, Gennarini F, Orio M, Le Poul N, Ottenwaelder X | 32073833 CHEMBIOCHEM |
| 10 | A bio-inspired synthesis of oxindoles by catalytic aerobic dual C-H functionalization of phenols. | Huang Z, Askari MS, Esguerra KVN, Dai TY, Kwon O, Ottenwaelder X, Lumb JP | 29861988 CHEMISTRY |
| 11 | Synthesis of Highly Functionalized Triarylbismuthines by Functional Group Manipulation and Use in Palladium- and Copper-Catalyzed Arylation Reactions. | Hébert M, Petiot P, Benoit E, Dansereau J, Ahmad T, Le Roch A, Ottenwaelder X, Gagnon A | 27231755 CHEMBIOCHEM |
| 12 | Supramolecular control of monooxygenase reactivity in a copper(ii) cryptate. | Chaloner L, Khomutovskaya A, Thomas F, Ottenwaelder X | 27328176 CHEMBIOCHEM |
| Title: | Mechanochemical Synthesis of Boroxine-linked Covalent Organic Frameworks | ||||
| Authors: | Hamzehpoor E, Effaty F, Borchers TH, Stein RS, Wahrhaftig-Lewis A, Ottenwaelder X, Frišcic T, Perepichka DF | ||||
| Link: | https://pubmed.ncbi.nlm.nih.gov/38970305/ | ||||
| DOI: | 10.1002/anie.202404539 | ||||
| Publication: | Angewandte Chemie (International ed. in English) | ||||
| Keywords: | Boroxines; Mechanochemistry; Porous materials; Resonant Acoustic Mixing; covalent organic frameworks; | ||||
| PMID: | 38970305 | Category: | Date Added: | 2024-07-06 | |
| Dept Affiliation: |
CHEMBIOCHEM
1 McGill University, Chemistry, CANADA. 2 Concordia University, Chemistry and Biochemistry, CANADA. 3 University of Birmingham, Chemistry, UNITED KINGDOM. 4 Bruker UK Ltd, Bruker UK Ltd, UNITED KINGDOM OF GREAT BRITAIN AND NORTHERN IRELAND. 5 McGill University, Department of Chemistry, 801 Sherbrooke Street West, H3A 0B8, Montreal, CANADA. |
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Description: |
We report a rapid, room-temperature mechanochemical synthesis of 2- and 3-dimensional boroxine covalent organic frameworks (COFs), enabled by using trimethylboroxine as a dehydrating additive to overcome the hydrolytic sensitivity of boroxine-based COFs. The resulting COFs display high porosity and crystallinity, with COF-102 being the first example of a mechanochemically prepared 3D COF, exhibiting a surface area of ca. 2,500 m2 g-1. Mechanochemistry enabled a >20-fold reduction in solvent use and ~100-fold reduction in reaction time compared with solvothermal methods, providing target COFs quantitatively with no additional work-up besides vacuum drying. Real-time Raman spectroscopy permitted the first quantitative kinetic analysis of COF mechanosynthesis, while transferring the reaction design to Resonant Acoustic Mixing (RAM) enabled synthesis of multi-gram amounts of the target COFs (tested up to 10 g). |
