Keyword search (4,163 papers available)

"Mal S" Authored Publications:

Title Authors PubMed ID
1 Charge separation in a copper(I) donor-chromophore-acceptor assembly for both photoanode and photocathode sensitization Singh Z; Chiong JD; Ricardo-Noordberg JF; Kamal S; Majewski MB; 39258478
CHEMBIOCHEM
2 Molecular copper(I)-sensitized photoanodes for alcohol oxidation under ambient conditions Ricardo-Noordberg J; Kamal S; Majewski M; 38932662
CHEMBIOCHEM
3 Effects of increasing ligand conjugation in Cu(I) photosensitizers on NiO semiconductor surfaces Singh Z; Chiong JD; Kamal S; Majewski MB; 38497406
CHEMBIOCHEM
4 Consistency of electrical source imaging in presurgical evaluation of epilepsy across different vigilance states Avigdor T; Abdallah C; Afnan J; Cai Z; Rammal S; Grova C; Frauscher B; 38217279
PERFORM
5 Luminescent studies of binuclear ternary europium(III) pyridineoxide tetrazolate complexes containing bis-phosphine oxide as auxiliary co-ligands. Mal S, Pietraszkiewicz M, Pietraszkiewicz O 29178666
CHEMBIOCHEM

 

Title:Molecular copper(I)-sensitized photoanodes for alcohol oxidation under ambient conditions
Authors:Ricardo-Noordberg JKamal SMajewski M
Link:https://pubmed.ncbi.nlm.nih.gov/38932662/
DOI:10.1002/cssc.202400611
Publication:ChemSusChem
Keywords:donor-chromophore-acceptorphotocatalysis, solar energy conversionphotoelectrochemistry
PMID:38932662 Category: Date Added:2024-06-27
Dept Affiliation: CHEMBIOCHEM
1 Concordia University, Chemistry and Biochemistry, CANADA.
2 University of British Columbia, Chemistry, CANADA.
3 Concordia University, Chemistry and Biochemistry, 7141 Sherbrook St W, H4B 1R6, Montreal, CANADA.

Description:

Dye-sensitized photoelectrochemical cells can enable the production of molecules currently accessible through energetically demanding syntheses. Copper(I)-based dyes represent electronically tunable charge transfer and separation systems. Herein, we report a Cu(I)-bisdiimine donor-chromophore-acceptor dye with an absorbance in the visible part of the solar spectrum composed of a phenothiazine electron donor, and dipyrido[3,2-a:2',3'-c]phenazine electron acceptor. This complex is incorporated onto a zinc oxide nanowire semiconductor surface effectively forming a photoanode that is characterized spectroscopically and electrochemically. We investigate the photo-oxidation of hydroquinone, and the photosensitization of 2,2,6,6-tetramethylpiperidine-1-oxyl and N-hydroxyphthalimide for the oxidation of furfuryl alcohol to furfuraldehyde, resulting in near quantitative conversions, with poor selectivity to the alcohol.





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