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PubMed Publications| Keyword search (4,163 papers available) |  |
"Bicalho HA" Authored Publications:
| Title: | Unravelling the synthesis of a rare-earth cluster-based metal-organic framework with spn topology | ||||
| Authors: | Bicalho HA, Saraci F, Velazquez-Garcia JJ, Titi HM, Howarth AJ | ||||
| Link: | https://pubmed.ncbi.nlm.nih.gov/36065793/ | ||||
| DOI: | 10.1039/d2cc03575h | ||||
| Publication: | Chemical communications (Cambridge, England) | ||||
| Keywords: | |||||
| PMID: | 36065793 | Category: | Date Added: | 2022-09-06 | |
| Dept Affiliation: |
CHEMBIOCHEM
1 Department of Chemistry and Biochemistry, Concordia University, 7141 Sherbrooke Street W., Montreal, QC, H4B 1R6, Canada. ashlee.howarth@concordia.ca. 2 Photo Science - Structural Dynamics in Chemical Systems, Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, Hamburg, 22607, Germany. 3 Department of Chemistry, McGill University, 801 Sherbrooke Street W., Montreal, QC, H3A 0B8, Canada. |
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Description: |
Y-CU-45, an analogue of Zr-MOF-808, is synthesized for the first time. Several reaction conditions are tested demonstrating that two fluorinated modulators are required for a reproducible synthesis yielding high quality material. Y-CU-45 shows high crystallinity and surface area, shining light on the potential for rare-earth cluster-based MOFs with open metal sites. |
