Keyword search (4,164 papers available)

"Askari MS" Authored Publications:

Title Authors PubMed ID
1 Overlap and Covalency in a κN-Arylnitrosyl Cu(II) Metalloradical Formed by Hydroxylamine Oxidative Binding MacKay A; Zsombor-Pindera J; Effaty F; Sheibany N; Gennarini F; Habibian M; Chen F; Askari MS; Brytskyi M; Kroeker S; Kennepohl P; Ottenwaelder X; 41524899
CHEMBIOCHEM
2 Sterically-Hindered Molecular p-Dopants Promote Integer Charge Transfer in Organic Semiconductors Charoughchi S; Liu JT; Berteau-Rainville M; Hase H; Askari MS; Bhagat S; Forgione P; Salzmann I; 37220083
CHEMBIOCHEM
3 Intramolecular H-bond stabilization of a primary hydroxylamine in salen-type metal complexes Singh H; MacKay A; Sheibany N; Chen F; Mosser M; Rouet PÉ; Rousseau F; Askari MS; Ottenwaelder X; 34545379
CHEMBIOCHEM
4 Tuning Inner-Sphere Electron Transfer in a Series of Copper/Nitrosoarene Adducts. Askari MS, Effaty F, Gennarini F, Orio M, Le Poul N, Ottenwaelder X 32073833
CHEMBIOCHEM
5 Facile Aqueous-Phase Synthesis of an Ultrasmall Bismuth Nanocatalyst for the Reduction of 4-Nitrophenol. Liang Y, Manioudakis J, Macairan JR, Askari MS, Forgione P, Naccache R 31552336
CHEMBIOCHEM
6 A bio-inspired synthesis of oxindoles by catalytic aerobic dual C-H functionalization of phenols. Huang Z, Askari MS, Esguerra KVN, Dai TY, Kwon O, Ottenwaelder X, Lumb JP 29861988
CHEMISTRY

 

Title:Intramolecular H-bond stabilization of a primary hydroxylamine in salen-type metal complexes
Authors:Singh HMacKay ASheibany NChen FMosser MRouet PÉRousseau FAskari MSOttenwaelder X
Link:https://pubmed.ncbi.nlm.nih.gov/34545379/
DOI:10.1039/d1cc03077a
Publication:Chemical communications (Cambridge, England)
Keywords:
PMID:34545379 Category: Date Added:2021-09-21
Dept Affiliation: CHEMBIOCHEM
1 Department of Chemistry and Biochemistry, Concordia University, Montreal, QC, Canada. dr.x@concordia.ca.

Description:

Primary hydroxylamines, RNHOH, decompose readily in the presence of transition metal ions. We show that this reactivity can be arrested by ligand design via an intramolecular hydrogen bond. Six metal complexes with an intact NHOH group were synthesized and crystallographically characterized. The Cu-hydroxylamine complexes can catalyze the aerobic oxidation of benzylic alcohols.





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