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Volatile organic compounds (VOCs) in urban areas are of great interest due to their significant role in forming ground-level ozone and adverse public health effects. Emission inventories usually compile the outdoor VOCs emission sources (e.g., traffic and industrial emissions). However, considering emissions from volatile chemical products (e.g., solvents, printing ink, personal care products) is challenging because of scattered data and the lack of an effective method to estimate the VOCs emission rate from these chemical products. This paper aims to systematically analyse potential sources of VOCs emission in Canada's built environment, including volatile chemical products. Also, spatial variation of VOCs level in the ambient atmosphere is examined to understand the VOC relationship with ozone and secondary organic aerosol formation. The study shows that VOCs level may vary among everyday microenvironments (e.g., residential areas, offices, and retail stores) depending on the frequency of product consumption, building age, ventilation condition, and background ambient concentration in the atmosphere. However, it is very difficult to establish VOC speciation and apportionment to different volatile chemical products that contribute most significantly to exposure and target subpopulations with elevated levels. Thus, tracer compounds can be used to identify inventory sources at the consumer end. A critical overview highlights the limitations of existing VOC estimation methods and possible approaches to control VOC emissions. The findings provide crucial information to establish an emission inventory framework for volatile chemical products at a national scale and enable policymakers to limit VOCs emission from various volatile chemical products.