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Butyl Acrylate/2-Methylene-1,3-Dioxepane/Vinyl Acetate Emulsion Terpolymerization: Incorporating Backbone Degradable Linkages into Adhesive Applications

Author(s): Meek K; Movafagh M; Dubé MA;

The ring-opening polymerization of bio-based monomer 2-methylene-1,3-dioxepane (MDO) can reportedly enhance polymer degradability. Butyl acrylate (BA)/MDO/vinyl acetate (VAc) terpolymers were synthesized via emulsion polymerization for their eventual application as pressure-sensitive adhesives (PSAs). While using MDO in emulsion polymerization leads to a ...

Article GUID: 39719378


Virtual reality-based preoperative planning for optimized trocar placement in thoracic surgery: A preliminary study

Author(s): Harirpoush A; Rakovich G; Kersten-Oertel M; Xiao Y;

Video-assisted thoracic surgery (VATS) is a minimally invasive approach for treating early-stage non-small-cell lung cancer. Optimal trocar placement during VATS ensures comprehensive access to the thoracic cavity, provides a panoramic endoscopic view, and prevents instrument crowding. While established principles such as the Baseball Diamond Principle (B ...

Article GUID: 39720764


Insights from multiple stable isotopes (C, N, Cl) into the photodegradation of herbicides atrazine and metolachlor

Author(s): Levesque-Vargas M; Ohlund L; Sleno L; Gélinas Y; Höhener P; Ponsin V;

Many processes can contribute to the attenuation of the frequently detected and toxic herbicides atrazine and metolachlor in surface water, including photodegradation. Multi-element compound-specific isotope analysis has the potential to decipher between these different degradation pathways as Cl is a promising tool for both pathway identification and a s ...

Article GUID: 39716600


The effect of micro-vessel viscosity on the resonance response of a two-microbubble system

Author(s): Yusefi H; Helfield B;

Clinical ultrasound contrast agent microbubbles remain intravascular and are between 1-8 µm in diameter, with a volume-weighted mean size of 2-3 µm. Despite their worldwide clinical utility as a diagnostic contrast agent, and their continued and ongoing success as a local therapeutic vector, the fundamental interplay between microbubbles - including bubbl ...

Article GUID: 39705920


Two-dimensional Nanosheets by Liquid Metal Exfoliation

Author(s): Bai Y; Xu Y; Sun L; Ward Z; Wang H; Ratnayake G; Wang C; Zhao M; He H; Gao J; Wu M; Lu S; Bepete G; Peng D; Liu B; Kang F; Terrones H; Terrones M; Lei Y;

Liquid exfoliation is a scalable and effective method for synthesizing 2D nanosheets (NSs) but often induces contamination and defects. Here, liquid metal gallium (Ga) is used to exfoliate bulk layered materials into 2D NSs at near room temperature, utilizing the liquid surface tension and Ga int ...

Article GUID: 39707650


Isotopic and molecular analyses of n-alkanes in a temporal study of coastal sediment contributions to organic carbon degradation induced by algal bloom and terrestrial runoff

Author(s): Mirzaei Y; Douglas PMJ; Gélinas Y;

The priming effect (PE) refers to the enhanced remineralization of recalcitrant organic carbon (OC) driven by the respiration of labile OC, potentially increasing CO2 fluxes from aquatic ecosystems. Patterns of PE induced by marine and terrestrial OC inputs can be explored through sedimentary contributions to the degraded OC pool. In this study, coastal s ...

Article GUID: 39700996


Editorial: Insight in non-pharmacological treatment of pain-2023

Author(s): Geoffrey Dover

No abstract available

Article GUID: 39697557


Oil spills in coastal regions of the Arctic and Subarctic: Environmental impacts, response tactics, and preparedness

Author(s): Bi H; Wang Z; Yue R; Sui J; Mulligan CN; Lee K; Pegau S; Chen Z; An C;

Coastal areas of the Arctic and Subarctic are vulnerable to accidental oil spills, impacting the ecosystem, society, and economy. This article provides a comprehensive overview of oil spill pollution issues in cold regions, focusing on environmental impacts, oil transport and fate, coastal/shoreline response measures, and the state of current internationa ...

Article GUID: 39689468


Asymmetric autocatalytic reactions and their stationary distribution

Author(s): Gallinger C; Popovic L;

We consider a general class of autocatalytic reactions, which has been shown to display stochastic switching behaviour (discreteness-induced transitions (DITs)) in some parameter regimes. This behaviour was shown to occur either when the overall species count is low or when the rate of inflow and outflow of species is relatively much smaller than the rate ...

Article GUID: 39679357


The Effects of Weekly Levels of Supervisor Support and Workload on Next Week Levels of Well-Being, Satisfaction, and Performance as Mediated by Weekend Work Recovery

Author(s): Cheyroux P; Morin AJS; Colombat P; Blechman Y; Gillet N;

This diary study sought to examine the direct and indirect effects of individuals' perceptions of supervisor support and workload during a work week (week 1) on their well-being, satisfaction, and performance at work during the following work week (week 2) as mediated through the quality of their weekend work recovery experiences (psychological detach ...

Article GUID: 39676703


Deep clustering analysis via variational autoencoder with Gamma mixture latent embeddings

Author(s): Guo J; Fan W; Amayri M; Bouguila N;

This article proposes a novel deep clustering model based on the variational autoencoder (VAE), named GamMM-VAE, which can learn latent representations of training data for clustering in an unsupervised manner. Most existing VAE-based deep clustering methods use the Gaussian mixture model (GMM) as a prior on the latent space. We employ a more flexible asy ...

Article GUID: 39662201


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