Early adolescents (aged 12-15) were observed during dyadic conflict discussions with their siblings (n = 23) and mothers (n = 32) in their homes. The verbal conflict behaviors and affect of family members were coded continuously. Sequential analyses identified temporal associations between individuals' affect and their own and their partners' verbal conflict behaviors. In addition, within-family and across-context similarities in behavior were examined. Results revealed that while many links between emotion and behavior were consistent with previous research (e.g., attack/assert when frowning/upset, withdraw/concede when sad), several differences emerged depending on the relationship (sibling vs. mother-adolescent) and position in the family (e.g., adolescent vs. mother). Furthermore, many within-family similarities were observed in responses to emotion, while adolescents showed few similarities in their behavior across contexts. Results are discussed in relation to the developmental context of early adolescence and family systems theory.