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Effects of delayed post-polymerization on physical, chemical, and biological properties of a 3D printing interim resin

Author(s): Choi Y; Comeau P; Lim BS; Manso AP; Chung SH;

Objectives: This study evaluated the effects of delayed post-polymerization on color, degree of conversion (DC), flexural strength (FS), and cellular response of a 3D-printed dental interim resin. Methods: Specimens were divided into six groups based on delays of 0 h, 2 h, 4 h, 6 h, 8 h, and 10 h before post-polymerization. Color was characterized using ...

Article GUID: 41152035


Anion Exchange Ionomer Binders for Alkaline Fuel Cells

Author(s): Gowling AC; Meek KM;

Anion exchange ionomer (AEI) binders are critical to the performance of alkaline electrochemical devices (i.e., fuel cells, electrolyzers, and batteries), as they facilitate ion transport, provide structural integrity, and improve the overall performance and lifespan of these devices. These binders not only ensure ion transport but also provide mechanical ...

Article GUID: 41010197


Engineered iron-sulfur carriers for efficient mixotrophic and sulfur autotrophic denitrification in low carbon to nitrogen ratio municipal wastewater: Mechanisms of biofilm enhancement and electron transfer promotion

Author(s): Yu S; Zhang X; Guo T; Li H; Liu W; Chen Z; Wang X; Ren B; Guo J;

Sulfur autotrophic denitrification (SAD) offers a sustainable solution for nitrogen removal in low carbon to nitrogen ratio (C/N) municipal wastewater, yet its efficiency and startup time pose significant challenges. To overcome these, we developed iron-sulfur-modified carriers (FeS@MC) and integrated them into an in-situ sequencing batch reactor (S-Fe-SB ...

Article GUID: 40712941


Stability of Acetals/Ketals Under Controlled Radical and Ring Opening Polymerization

Author(s): Andrade-Gagnon B; Casillas-Popova SN; Oh JK;

Well-defined acid-degradable amphiphilic block copolymers (ABPs) and their nanoassemblies labeled with acid-labile groups have been developed for smart drug delivery, exhibiting controlled/enhanced release of therapeutics in tumoral tissues and endo/lysosomes. In general, controlled polymerization techniques, particularly atom transfer radical polymerizat ...

Article GUID: 40614241


PEDOT:PSS-MWCNT Nanocomposite Wire for Routing in Energy Harvesting Devices

Author(s): Shafagh SH; Deen I; Mamsapuram Panneerselvam D; Packirisamy M;

Polydimethylsiloxane (PDMS) and poly(3,4-ethylene dioxythiophene):poly(4-styrene-sulfonate) (PEDOT:PSS) composites were tested to determine their suitability for charging small-scale batteries in conjunction with a piezoelectric actuator as an energy harvester. Two different PEDOT:PSS patterns (zigzag and serpentine) were tested, and the maximum DC voltag ...

Article GUID: 40283259


Hyperbranched Polyethylene Ionomers Containing Quaternary Ammonium Ions and Their Functionalization of Nanomaterials

Author(s): Ye Z; Rahmatinejad J; Raisi B; Dai P;

Ionomers containing a small number of ionic side groups are a unique class of polymers with some valuable properties and distinct applications. To date, commercially important ionomers are exclusively anionomers that contain covalently bonded anions and are synthesized commonly by radical polymerization. The catalytic synthesis of polyethylene-based catio ...

Article GUID: 40214570


Butyl Acrylate/2-Methylene-1,3-Dioxepane/Vinyl Acetate Emulsion Terpolymerization: Incorporating Backbone Degradable Linkages into Adhesive Applications

Author(s): Meek K; Movafagh M; Dubé MA;

The ring-opening polymerization of bio-based monomer 2-methylene-1,3-dioxepane (MDO) can reportedly enhance polymer degradability. Butyl acrylate (BA)/MDO/vinyl acetate (VAc) terpolymers were synthesized via emulsion polymerization for their eventual application as pressure-sensitive adhesives (PSAs). While using MDO in emulsion polymerization leads to a ...

Article GUID: 39719378


Research Trends in the Development of Block Copolymer-Based Biosensing Platforms

Author(s): Chung YH; Oh JK;

Biosensing technology, which aims to measure and control the signals of biological substances, has recently been developed rapidly due to increasing concerns about health and the environment. Top-down technologies have been used mainly with a focus on reducing the size of biomaterials to the nano-level. However, bottom-up technologies such as self-assembl ...

Article GUID: 39590001


Ce-doped MnOx mixed with polyvinylidene fluoride as an amplified ozone decomposition filter medium in humid conditions

Author(s): Namdari M; Haghighat F; Lee CS;

Ozone is a hazardous air pollutant with significant adverse effects on human health and the environment. With the growing industrial use of ozone, effective ozone removal systems have become essential, especially to protect workers' health. MnOx-based catalysts offer substantial promise for ozone decomposition; however, a major challenge in their appl ...

Article GUID: 39579188


Bulk Free Radical Terpolymerization of Butyl Acrylate, 2-Methylene-1,3-Dioxepane and Vinyl Acetate: Terpolymer Reactivity Ratio Estimation

Author(s): Movafagh M; Meek KM; Scott AJ; Penlidis A; Dubé MA;

This investigation introduces the first estimation of ternary reactivity ratios for a butyl acrylate (BA), 2-methylene-1,3-dioxepane (MDO), and vinyl acetate (VAc) system at 50 °C, with an aim to develop biodegradable pressure-sensitive adhesives (PSAs). In this study, we applied the error-in-variables model (EVM) to estimate reactivity ratios. The ternar ...

Article GUID: 38794524


Design, Synthesis, and Acid-Responsive Disassembly of Shell-Sheddable Block Copolymer Labeled with Benzaldehyde Acetal Junction

Author(s): Andrade-Gagnon B; Casillas-Popova SN; Jazani AM; Oh JK;

Smart nanoassemblies degradable through the cleavage of acid-labile linkages have attracted significant attention because of their biological relevance found in tumor tissues. Despite their high potential to achieve controlled/enhanced drug release, a systematic understanding of structural factors that affect their pH sensitivity remains challenging, part ...

Article GUID: 38499007


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