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Exploring global oceanic persistence and ecological effects of legacy persistent organic pollutants across five decades

Author(s): Zhang X; Li L; Xie Z; Ma J; Li YF; Cai M; Ren NQ; Kallenborn R; Zhang ZF; Zhang X; C G Muir D;

Global monitoring of persistent organic pollutants (POPs) has intensified following regulatory efforts aimed at reducing their release. In this context, we compiled over 10,000 POP measurements, reported from 1980 to 2023, to assess the effectiveness of these legislative measures in the global ma ...

Article GUID: 39321284


Superhydrophilic CoFe Dispersion of Hydrogel Electrocatalysts for Quasi-Solid-State Photoelectrochemical Water Splitting

Author(s): Wang H; Gao RT; Nguyen NT; Bai J; Ren S; Liu X; Zhang X; Wang L;

Photoelectrochemical (PEC) water splitting is an attractive strategy to convert solar energy to hydrogen. However, the lifetime of PEC devices is restricted by the photocorrosion of semiconductors and the instability of co-catalysts. Herein, we report a feasible in situ inherent cross-linking method for stabilizing semiconductors that uses a CoFe-disperse ...

Article GUID: 37901939


Hydroxyl radical production by abiotic oxidation of pyrite under estuarine conditions: The effects of aging, seawater anions and illumination

Author(s): Liu R; Dai Y; Feng Y; Sun S; Zhang X; An C; Zhao S;

Pyrite is widely distributed in estuarine sediments as an inexpensive natural Fenton-like reagent, however, the mechanism on the hydroxyl radical (HO·) production by pyrite under estuarine environmental conditions is still poorly understood. The batch experiments were performed to investigate the effects of estuarine conditions including aging (in air, in ...

Article GUID: 37778841


1T-2H Mixed-Phase MoS2 Stabilized with a Hyperbranched Polyethylene Ionomer for Mg2+ /Li+ Co-Intercalation Toward High-Capacity Dual-Salt Batteries

Author(s): Rahmatinejad J; Raisi B; Liu X; Zhang X; Sadeghi Chevinli A; Yang L; Ye Z;

Dual-salt magnesium/lithium-ion batteries (MLIBs) benefit from fast lithium ion diffusion on the cathode side while providing safety due to the dendrite-free Mg2+ stripping/plating mechanism on the anode side. Bulk MoS2 (B-MoS2 ), as a cathode for magnesium-ion batteries (MIBs), suffers from low conductivity and relatively van der Waals gaps and, conseque ...

Article GUID: 37691015


Dynamic semiconductor-electrolyte interface for sustainable solar water splitting over 600 hours under neutral conditions

Author(s): Gao RT; Nguyen NT; Nakajima T; He J; Liu X; Zhang X; Wang L; Wu L;

Photoelectrochemical (PEC) water splitting that functions in pH-neutral electrolyte attracts increasing attention to energy demand sustainability. Here, we propose a strategy to in situ form a NiB layer by tuning the composition of the neutral electrolyte with the additions of nickel and borate species, which improves the PEC performance of the BiVO4 phot ...

Article GUID: 36598972


A Small Molecule Inhibitor of Erg251 Makes Fluconazole Fungicidal by Inhibiting the Synthesis of the 14α-Methylsterols

Author(s): Lu H; Li W; Whiteway M; Wang H; Zhu S; Ji Z; Feng Y; Yan L; Fang T; Li L; Ni T; Zhang X; Lv Q; Ding Z; Qiu L; Zhang D; Jiang Y;

Fluconazole (FLC) is widely used to prevent and treat invasive fungal infections. However, FLC is a fungistatic agent, allowing clinical FLC-susceptible isolates to tolerate FLC. Making FLC fungicidal in combination with adjuvants is a promising strategy to avoid FLC resistance and eliminate the ...

Article GUID: 36475771


Air monitoring of tire-derived chemicals in global megacities using passive samplers

Author(s): Johannessen C; Saini A; Zhang X; Harner T;

Pollution from vehicle tires has received world-wide research attention due to its ubiquity and toxicity. In this study, we measured various tire-derived contaminants semi-quantitatively in archived extracts of passive air samplers deployed in 18 major cities that comprise the Global Atmospheric Passive Sampling (GAPS) Network (GAPS-Megacities). Analysis ...

Article GUID: 36152723


Perfluoroalkyl and polyfluoroalkyl substances (PFASs) in groundwater: current understandings and challenges to overcome

Author(s): Zhao Z; Li J; Zhang X; Wang L; Wang J; Lin T;

Perfluoroalkyl and polyfluoroalkyl substances (PFASs) have been frequently detected in groundwater globally. With the phase-out of perfluorooctane sulfonate (PFOS) and perfluorooctanate (PFOA) due to their risk to the ecosystem and human population, various novel PFASs have been used as replacements and detected in groundwater. In order to summarize the c ...

Article GUID: 35593984


Polycyclic Aromatic Hydrocarbons in the Marine Atmosphere from the Western Pacific to the Southern Ocean: Spatial Variability, Gas/Particle Partitioning, and Source Apportionment

Author(s): Zhang X; Zhang ZF; Zhang X; Zhu FJ; Li YF; Cai M; Kallenborn R;

The spatial variability of polycyclic aromatic hydrocarbons (PAHs) in the marine atmosphere contributes to the understanding of the global sources, fate, and impact of this contaminant. Few studies conducted to measure PAHs in the oceanic atmosphere have covered a large scale, especially in the Southern Ocean. In this study, high-volume air samples were t ...

Article GUID: 35476391


Indoor exposure to selected flame retardants and quantifying importance of environmental, human behavioral and physiological parameters

Author(s): Li Z; Zhang X; Wang B; Shen G; Zhang Q; Zhu Y;

Indoor exposure to organic flame retardants (FRs) has raised extensive concern due to associated adverse health effects. Indoor-exposure induced daily intakes of six widely used FRs individually ranged 0.002-611 ng/day and 0.02-463 ng/day, respectively, for adults and 2-6-year-old children; and resulting internal exposure levels ranged 0.1-159 and 2.1-450 ...

Article GUID: 35461943


Pesticides in the atmosphere and seawater in a transect study from the Western Pacific to the Southern Ocean: The importance of continental discharges and air-seawater exchange

Author(s): Zhang X; Zhang X; Zhang ZF; Yang PF; Li YF; Cai M; Kallenborn R;

The global oceans are known as terminal sink or secondary source for diffusive emission of organochlorine pesticides (OCPs) and selected current used pesticides (CUPs) into the overlaying atmosphere. Many pesticides have been widely produced worldwide, subsequently applied, and released into the environment. However, information on the occurrence patterns ...

Article GUID: 35452973


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