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Revisiting Homochiral versus Heterochiral Interactions through a Long Detective Story of a Useful Azobis-Nitrile and Puzzling Racemate

Author(s): García de la Concepción J; Flores-Jiménez M; Cuccia LA; Light ME; Viedma C; Cintas P;

This paper documents and reinvestigates the solid-state and crystal structures of 4,4'-azobis-4-cyanopentanoic acid (ACPA), a water-soluble azobis-nitrile of immense utility as a radical initiator in living polymerizations and a labile mechanophore that can be embedded within long polymer chains to undergo selective scission under mechanical activatio ...

Article GUID: 37547876


On the Origin of Sugar Handedness: Facts, Hypotheses and Missing Links-A Review

Author(s): Martínez RF; Cuccia LA; Viedma C; Cintas P;

By paraphrasing one of Kipling's most amazing short stories (How the Leopard Got His Spots), this article could be entitled "How Sugars Became Homochiral". Obviously, we have no answer to this still unsolved mystery, and this perspective simply brings recent models, experiments and hypotheses into the homochiral homogeneity of sugars on earth. We shal ...

Article GUID: 35796896


Pasteur made simple - mechanochemical transformation of racemic amino acid crystals into racemic conglomerate crystals.

Author(s): Viedma C, Lennox C, Cuccia LA, Cintas P, Ortiz JE

Chem Commun (Camb). 2020 Mar 23;: Authors: Viedma C, Lennox C, Cuccia LA, Cintas P, Ortiz JE

Article GUID: 32202285


Oriented attachment by enantioselective facet recognition in millimeter-sized gypsum crystals.

Author(s): Viedma C, Cuccia LA, McTaggart A, Kahr B, Martin AT, McBride JM, Cintas P

Chem Commun (Camb). 2016 Sep 22;52(78):11673-11676 Authors: Viedma C, Cuccia LA, McTaggart A, Kahr B, Martin AT, McBride JM, Cintas P

Article GUID: 27722508


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