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Unravelling the synthesis of a rare-earth cluster-based metal-organic framework with spn topology

Author(s): Bicalho HA; Saraci F; Velazquez-Garcia JJ; Titi HM; Howarth AJ;

Y-CU-45, an analogue of Zr-MOF-808, is synthesized for the first time. Several reaction conditions are tested demonstrating that two fluorinated modulators are required for a reproducible synthesis yielding high quality material. Y-CU-45 shows high crystallinity and surface area, shining light on the potential for rare-earth cluster-based MOFs with open m ...

Article GUID: 36065793


Rare-earth metal-organic frameworks: from structure to applications.

Author(s): Saraci F, Quezada-Novoa V, Donnarumma PR, Howarth AJ

Chem Soc Rev. 2020 Jul 13;: Authors: Saraci F, Quezada-Novoa V, Donnarumma PR, Howarth AJ

Article GUID: 32658241


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