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Resonant acoustic mixing (RAM) for efficient mechanoredox catalysis without grinding or impact media

Author(s): Effaty F; Gonnet L; Koenig SG; Nagapudi K; Ottenwaelder X; Frišcic T;

Resonant acoustic mixing (RAM) enables mechanoredox catalysis with BaTiO3 as the piezoelectric catalyst on model diazonium coupling reactions. RAM proceeds without formal grinding or impact media, is faster than the analogous ball-milling strategy, and is readily scalable. X-ray diffraction and spectroscopy indicate that reusability of BaTiO3 as a mechano ...

Article GUID: 36546478


Simple, scalable mechanosynthesis of metal-organic frameworks using liquid-assisted resonant acoustic mixing (LA-RAM)

Author(s): Titi HM; Do JL; Howarth AJ; Nagapudi K; Frišcic T;

We present a rapid and readily scalable methodology for the mechanosynthesis of diverse metal-organic frameworks (MOFs) in the absence of milling media typically required for other types of mechanochemical syntheses. We demonstrate the use of liquid-assisted resonant acoustic mixing (LA-RAM) methodology for the synthesis of three- and two-dimensional MOFs ...

Article GUID: 34094134


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