Author(s): Singh Z; Chiong JD; Ricardo-Noordberg JF; Kamal S; Majewski MB;
A copper(I) donor-chromophore-acceptor triad bearing 1,8-napthalenemonoimide as the electron acceptor and triphenylamine as the electron donor was synthesized. Photophysical and electrochemical characterization suggest stepwise photoinduced charge separation upon excitation of the copper(I)-based metal-to-ligand charge transfer (MLCT) transition. Analyses ...
Article GUID: 39258478
Author(s): Ricardo-Noordberg J; Kamal S; Majewski M;
Dye-sensitized photoelectrochemical cells can enable the production of molecules currently accessible through energetically demanding syntheses. Copper(I)-based dyes represent electronically tunable charge transfer and separation systems. Herein, we report a Cu(I)-bisdiimine donor-chromophore-acceptor dye with an absorbance in the visible part of the sola ...
Article GUID: 38932662
Author(s): Singh Z; Chiong JD; Kamal S; Majewski MB;
Dye-sensitized photoelectrodes may be used as heterogeneous components for fuel-forming reactions in photoelectrochemical cells. There has been increasing interest in developing Earth-abundant cheaper photosensitizers based on first-row transition metals. We describe here the synthesis, characterization, and study of the ground and excited state propertie ...
Article GUID: 38497406
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