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From inert to explosive, the hydrolytic reactivity of R-NSO compounds understood: a computational study

Author(s): Ivanova EV; Muchall HM;

We present a computational study on the concerted hydrolysis of several classes of N-sulfinylamines of generic formula R-N-S-O, such as the -amines themselves (R-NSO), -hydrazines (R-NH-NSO), -hydrazides (R-CO-NH-NSO) and -amides (R-CO-NSO), as these species are known to possess a wide range of hydrolytic reactivity. Two possible mechanisms of hydrolysis, ...

Article GUID: 21428403


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