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Sterically-Hindered Molecular p-Dopants Promote Integer Charge Transfer in Organic Semiconductors

Author(s): Charoughchi S; Liu JT; Berteau-Rainville M; Hase H; Askari MS; Bhagat S; Forgione P; Salzmann I;

Molecular p-dopants designed to undergo electron transfer with organic semiconductors are typically planar molecules with high electron affinity. However, their planarity can promote the formation of ground-state charge transfer complexes with the semiconductor host and results in fractional inst ...

Article GUID: 37220083


Intramolecular H-bond stabilization of a primary hydroxylamine in salen-type metal complexes

Author(s): Singh H; MacKay A; Sheibany N; Chen F; Mosser M; Rouet PÉ; Rousseau F; Askari MS; Ottenwaelder X;

Primary hydroxylamines, RNHOH, decompose readily in the presence of transition metal ions. We show that this reactivity can be arrested by ligand design via an intramolecular hydrogen bond. Six metal complexes with an intact NHOH group were synthesized and crystallographically characterized. The ...

Article GUID: 34545379


Tuning Inner-Sphere Electron Transfer in a Series of Copper/Nitrosoarene Adducts.

Author(s): Askari MS, Effaty F, Gennarini F, Orio M, Le Poul N, Ottenwaelder X

Inorg Chem. 2020 Feb 19;: Authors: Askari MS, Effaty F, Gennarini F, Orio M, Le Poul N, Ottenwaelder X

Article GUID: 32073833


Facile Aqueous-Phase Synthesis of an Ultrasmall Bismuth Nanocatalyst for the Reduction of 4-Nitrophenol.

Author(s): Liang Y, Manioudakis J, Macairan JR, Askari MS, Forgione P, Naccache R

ACS Omega. 2019 Sep 17;4(12):14955-14961 Authors: Liang Y, Manioudakis J, Macairan JR, Askari MS, Forgione P, Naccache R

Article GUID: 31552336


A bio-inspired synthesis of oxindoles by catalytic aerobic dual C-H functionalization of phenols.

Author(s): Huang Z, Askari MS, Esguerra KVN, Dai TY, Kwon O, Ottenwaelder X, Lumb JP

Chem Sci. 2016 Jan 01;7(1):358-369 Authors: Huang Z, Askari MS, Esguerra KVN, Dai TY, Kwon O, Ottenwaelder X, Lumb JP

Article GUID: 29861988


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