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Amphiphilicity of Tetraazaporphyrins Containing Four Terminal Carboxylic Acid and Four Alkyl Groups Promotes Face-On Orientation in Langmuir Films

Author(s): Alinia Z; Abdulhamied E; Selmani S; Miclette Lamarche R; Eichhorn SH; DeWolf CE;

Control over the orientation of polycyclic aromatic dyes in thin films is paramount to tailoring their optical, electronic, and mechanical properties. Their supramolecular assembly in films is tuned here by converting the macrocyclic dyes to large amphiphiles. Two octaalkythio-substituted tetraazaporphyrins (TAPs) with one 5-carboxypentyl and one pentyl o ...

Article GUID: 39623767


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