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Mechanochemistry for Metal-Organic Frameworks and Covalent-Organic Frameworks (MOFs, COFs): Methods, Materials, and Mechanisms

Author(s): Marrett JM; Effaty F; Ottenwaelder X; Frišcic T;

The mechanochemistry of metal-organic frameworks (MOFs) is a well-established field whose development has advanced the understanding and the design of both MOF materials and mechanochemical reactions. This review outlines the close and mutually beneficial interplay of these two fields over the past two decades, including the description of mechanochemical ...

Article GUID: 40708349


Mechanochemical Synthesis of Boroxine-linked Covalent Organic Frameworks

Author(s): Hamzehpoor E; Effaty F; Borchers TH; Stein RS; Wahrhaftig-Lewis A; Ottenwaelder X; Frišcic T; Perepichka DF;

We report a rapid, room-temperature mechanochemical synthesis of 2- and 3-dimensional boroxine covalent organic frameworks (COFs), enabled by using trimethylboroxine as a dehydrating additive to overcome the hydrolytic sensitivity of boroxine-based COFs. The resulting COFs display high porosity a ...

Article GUID: 38970305


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