1 Faculty of Engineering and Applied Science, University of Regina, Regina, Saskatchewan, S4S 0A2, Canada; Institute for Energy, Environment and Sustainable Communities, University of Regina, Regina, Saskatchewan, S4S 0A2, Canada.
2 Faculty of Engineering and Applied Science, University of Regina, Regina, Saskatchewan, S4S 0A2, Canada; International Society for Environmental Information Sciences, 9803A Jingshidasha-BNU, 19 Xinwaidajie, Beijing 100875, China. Electronic address: huangg@uregina.ca.
3 School of Environment, Beijing Normal University, Beijing, 100875, China.
4 Department of Building, Civil and Environmental Engineering, Concordia University, Montreal, Quebec, H3G 1M8, Canada.
5 Canadian Light Source, Saskatoon, S7N 2V3, Canada.

Functional PVDF ultrafiltration membrane for Tetrabromobisphenol-A (TBBPA) removal with high water recovery.

Water Res. 2020 May 18;181:115952

Authors: Chen X, Huang G, Li Y, An C, Feng R, Wu Y, Shen J

Abstract

Tetrabromobisphenol-A (TBBPA) is one of the most important brominated flame retardants (BFRs), accounting for 60% of the total commercial BFR market. Increasing amounts of TBBPA and byproducts are released to the aquatic environment due to their extensive utilization in various sectors. However, research on the treatment of TBBPA contaminated wastewater using membrane filtration is still lacked. Herein, a PVDF10-PAA-ZrO2 membrane was successfully developed and applied for the treatment of high-concentration TBBPA wastewater with super-high water recovery. The membrane was obtained through surface functionalization with nano-ZrO2 from commercial PVDF ultrafiltration (UF) membrane. Compared to the commercial PVDF membrane, the developed membrane exhibited 4 times of permeate flux which was up to 200 L/m2 min with comparable TBBPA rejection rate. Furthermore, the mechanisms of membrane development and TBBPA rejection were explored through synchrotron-based ATR-FTIR and X-ray analyses. It was revealed that ZrO2 NPs were immobilized into membrane surface through binding with PAA layer, where the O of the carboxyl group combined with the Zr4+ on the ZrO2 NP surface to form C-O-Zr bond through monodentate and bridging-bidentate modes. The sieving function of membrane could be the main mechanism of TBBPA removal. This research demonstrated a practical route and solid insight toward the development of highly efficient membrane for TBBPA removal. The proposed PVDF10-PAA-ZrO2 membrane can also be promising for other industrial separation and purification applications.

PMID: 32497754 [PubMed - as supplied by publisher]