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Charge separation in a copper(I) donor-chromophore-acceptor assembly for both photoanode and photocathode sensitization

Author(s): Singh Z; Chiong JD; Ricardo-Noordberg JF; Kamal S; Majewski MB;

A copper(I) donor-chromophore-acceptor triad bearing 1,8-napthalenemonoimide as the electron acceptor and triphenylamine as the electron donor was synthesized. Photophysical and electrochemical characterization suggest stepwise photoinduced charge separatio ...

Article GUID: 39258478


Effects of increasing ligand conjugation in Cu(I) photosensitizers on NiO semiconductor surfaces

Author(s): Singh Z; Chiong JD; Kamal S; Majewski MB;

Dye-sensitized photoelectrodes may be used as heterogeneous components for fuel-forming reactions in photoelectrochemical cells. There has been increasing interest in developing Earth-abundant cheaper photosensitizers based on first-row transition metals. W ...

Article GUID: 38497406


A historical perspective on porphyrin-based metal-organic frameworks and their applications

Author(s): Zhang X; Wasson MC; Shayan M; Berdichevsky EK; Ricardo-Noordberg J; Singh Z; Papazyan EK; Castro AJ; Marino P; Ajoyan Z; Chen Z; Islamoglu T ...

Porphyrins are important molecules widely found in nature in the form of enzyme active sites and visible light absorption units. Recent interest in using these functional molecules as building bloc ...

Article GUID: 33678810


Molecular Copper(I)-Copper(II) Photosensitizer-Catalyst Photoelectrode for Water Oxidation.

Author(s): Singh Z, Donnarumma PR, Majewski MB

Copper(II)-based electrocatalysts for water oxidation in aqueous solution have been studied previously, but photodriving these systems still remains a challenge. In this work, a bis(diimine)copper(I)-based donor-chromophore-acceptor system is synthesized an ...

Article GUID: 32909755


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