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Synthesis, Characterization and Photophysical Properties of a New Family of Rare-earth Cluster-based Metal-organic Frameworks

Author(s): Bicalho HA; Copeman C; Barbosa HP; Donnarumma PR; Davis Z; Quezada-Novoa V; Velazquez-Garcia JJ; Liu N; Hemmer E; Howarth AJ; ...

In this work, nine new rare-earth metal-organic frameworks (RE-MOFs, where RE = Lu(III), Yb(III), Tm(III), Er(III), Ho(III), Dy(III), Tb(III), Gd(III), and Eu(III)) isostructural to Zr-MOF-808 are ...

Article GUID: 39105655


Rare-earth acetates as alternative precursors for rare-earth cluster-based metal-organic frameworks

Author(s): Richezzi M; Donnarumma PR; Copeman C; Howarth AJ;

RE-UiO-66 analogues are synthesized using RE acetates as precursors for the first time. These MOFs are fully characterized and the influence of the precursor on the materials obtained is studied. Additionally, the influence of water on the yield of the synt ...

Article GUID: 38646995


Morphology Control of Self-Assembled Copper Coordination Polymers for Glucose Assays

Author(s): Van Houten J; Dosajh A; Gulati S; Bhullar G; Copeman C; Ogata AF;

Low-cost analytical assays enable accessible detection of clinically and environmentally important analytes; however, common enzyme-based assays suffer from high production and storage costs. Catalytically active synthetic materials serve as replacements fo ...

Article GUID: 38320270


Adsorptive removal of iodate oxyanions from water using a Zr-based metal-organic framework

Author(s): Copeman C; Bicalho HA; Terban MW; Troya D; Etter M; Frattini PL; Wells DM; Howarth AJ;

A Zr6-based metal-organic framework (MOF), MOF-808, is investigated for the adsorptive removal of IO3- from aqueous solutions, due to its high surface area and abundance of open metal sites. The uptake kinetics, adsorption capacity and binding mode are stud ...

Article GUID: 36753325


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