Author(s): Singh Z; Chiong JD; Ricardo-Noordberg JF; Kamal S; Majewski MB;

A copper(I) donor-chromophore-acceptor triad bearing 1,8-napthalenemonoimide as the electron acceptor and triphenylamine as the electron donor was synthesized. Photophysical and electrochemical characterization suggest stepwise photoinduced charge separation upon excitation of the copper(I)-based metal-to-ligand charge transfer (MLCT) transition. Analyses ...

Article GUID: 39258478

Author(s): Singh Z; Chiong JD; Kamal S; Majewski MB;

Dye-sensitized photoelectrodes may be used as heterogeneous components for fuel-forming reactions in photoelectrochemical cells. There has been increasing interest in developing Earth-abundant cheaper photosensitizers based on first-row transition metals. We describe here the synthesis, characterization, and study of the ground and excited state propertie ...

Article GUID: 38497406